Which of the following compounds gives rapid hardening with an early gain in strength with a higher heat of hydration in OPC Cement?
🧪 Understanding Bogue's Compounds
The properties of cement are governed by the relative proportions of four main chemical compounds, known as Bogue's compounds. Each compound hydrates at a different rate and contributes differently to the cement's final properties like strength, setting time, and heat generation.
- Tricalcium Silicate (C₃S): Responsible for early strength gain.
- Dicalcium Silicate (Câ‚‚S): Responsible for long-term, ultimate strength.
- Tricalcium Aluminate (C₃A): Responsible for the initial "flash" set.
- Tetracalcium Aluminoferrite (Câ‚„AF): Acts mainly as a flux and has poor cementing value.
🔬 Detailed Analysis of the Options
The question asks for the compound that provides rapid hardening, early gain in strength, and higher heat of hydration. We need to find the best fit for all three criteria.
A. C₃S (Tricalcium Silicate)
This is the best answer. C₃S is the primary contributor to the strength of cement in the first 28 days. It hydrates relatively quickly, leading to "rapid hardening" and a significant "early gain in strength." It also has a high heat of hydration, second only to C₃A. Because it is the main driver of the early strength development, it is the most fitting answer for the combination of properties mentioned.
B. C₃A (Tricalcium Aluminate)
This is a close but incorrect answer. C₃A reacts almost instantaneously with water, causing the "initial set" or "flash set." It also has the highest heat of hydration of all the compounds. However, its contribution to the actual strength of the cement is very minimal. The question specifically asks for "early gain in strength," which is the domain of C₃S, not C₃A. Therefore, while it is rapid and generates high heat, it fails on the critical "strength gain" criterion.
C. Câ‚‚S (Dicalcium Silicate)
This is incorrect. Câ‚‚S hydrates very slowly. Its contribution to strength is negligible in the early stages (the first week). It is primarily responsible for the progressive increase in strength after 28 days, often referred to as the "ultimate strength." It also has a very low heat of hydration.
D. Câ‚„AF (Tetracalcium Aluminoferrite)
This is incorrect. Câ‚„AF has the poorest cementing value of the four compounds. While it reacts relatively quickly, its contribution to strength is minimal. It primarily acts as a fluxing agent in the kiln, helping to reduce the clinkering temperature.
📊 Summary: Properties of Bogue's Compounds
| Compound (Name) | Typical % | Rate of Reaction | Strength Contribution | Heat of Hydration |
|---|---|---|---|---|
| C₃S (Alite) | 30-50% | Fast | Early Strength (1-28 days) | High |
| Câ‚‚S (Belite) | 20-45% | Slow | Ultimate Strength (>28 days) | Low |
| C₃A (Celite) | 8-12% | Very Fast (Flash Set) | Negligible | Very High |
| Câ‚„AF (Felite) | 6-10% | Moderate | Very Low | Moderate |
💡 Study Tips
- S is for Strength: Remember that the Silicates (C₃S and C₂S) are the primary strength-givers. C₃S gives early strength, while C₂S gives later (ultimate) strength.
- A is for Aluminate (and Action!): C₃A is all about fast action. It causes the initial set and generates the most heat, but contributes little to strength. It's also the compound most vulnerable to chemical (sulphate) attack.
- Read Carefully: Pay close attention to the wording. "Initial set" points to C₃A, but "early strength" points decisively to C₃S.