Engineering Materials·MCQ explained

Good cement contains

Try it first: pick an option, then read the explanation.

Correct answer: A. high percentage of C3S

Detailed Explanation: Role of C3S in Cement Quality

Portland cement is made up of four main clinker compounds: C3S (alite), C2S (belite), C3A (aluminate), and C4AF (ferrite). Each compound hydrates at a different rate and contributes to concrete strength, heat evolution, and durability differently.

Why A (high C3S) defines a good cement: C3S is the single most important compound in Portland cement. It reacts rapidly with water to produce C-S-H gel (the main strength-giving phase) and calcium hydroxide. C3S governs both the rate and magnitude of early strength gain (first 28 days). Ordinary Portland Cement (OPC) typically contains 45–65% C3S. High C3S variants (like rapid-hardening cement) exceed 65%. Options B, C, D: C2S is slow-reacting; C3A must be limited (it causes sulphate attack susceptibility and rapid early reaction); C4AF contributes little to strength.

Bogue Compounds in Portland Cement

CompoundFormula% in OPCRole
C3S (Alite)Ca3SiO545–65%Early + final strength (key compound)
C2S (Belite)Ca2SiO415–30%Late strength (slow hydration)
C3A (Aluminate)Ca3Al2O65–12%Very early flash set; heat; sulphate vulnerability
C4AF (Ferrite)Ca4Al2Fe2O108–12%Minor strength; grey colour in cement

Key Concepts for Students

  • C3S = strength: this is the most tested fact about cement compounds in civil engineering exams.
  • Rapid-hardening cement (RHC / IS 8041) has higher C3S and finer grinding to accelerate early strength.
  • C3A must be limited to ≤5% in sulphate-resistant cement to prevent expansive ettringite formation in sulphate environments.